青藏高原西部阿汝冰芯记录的近100 a气温变化研究   总被引：2，自引：2，他引：0  

杨丹丹  姚檀栋  邬光剑  朱美林  德吉 《冰川冻土》2021,43(1):124-134

以2017年9月钻取自青藏高原西部阿汝冰崩区长度55.29 m的阿汝冰芯为研究对象,通过冰芯δ¹⁸O记录与Nye模型重建了冰芯上部17.87 m的时间序列是1917—2016年。结合冰芯邻近的改则、狮泉河气象站1973—2016年夏季平均气温数据,通过相关性分析及线性回归法、Mann-Kendall（M-K）检验分析,发现冰芯与气象站记录的过去44年气温显著升高;根据M-K突变检验得出,20世纪80年代是气温变化由高—低—高的转折时期,且阿汝冰芯记录的突变年份1981年前后气温上升约1.97 ℃。同样地,采用线性回归法、M-K检验分析阿汝冰芯与邻近的古里雅冰芯共同记录的1917—1991年气温变化情况,发现两支冰芯记录的75年间气温变化总体呈上升趋势;根据M-K突变检验得出,升温始于20世纪30年代中后期并于50年代达到显著升温的趋势,且阿汝冰芯记录的突变年份1949年前后气温上升了约1.1 ℃。阿汝冰芯与气象站和古里雅冰芯记录的气温变化具有一致的升温趋势,但阿汝冰芯记录的增温幅度比气象站记录高,同时比古里雅冰芯记录的增温幅度小。  相似文献   

运用H、O同位素分析石阡地区地热水来源     

李永康  陈正山  王甘露 《水文》2021,41(1):28-34

通过对贵州省石阡地区地热水、冷泉及河流的地热地质条件、水化学成分及氢氧同位素分析,对该地区的地热水、冷泉及河流的水化学特征、来源及石阡地区的补给模式进行了研究。温泉水属于低中矿化度的弱碱性水;温泉群中阳离子以Ca^2+、Mg^2+为主,阴离子以SO4^2-和HCO3^-为主,研究区水化学类型主要为HCO3-Ca和SO4.HCO3-Ca型。区域内地热水中δ18O值为-9.32‰~-6.81‰,δD为-64.4‰~-44.9‰;冷泉及河流中δ18O值为-7.51‰~-6.00‰,δD为-50.7‰~-38.2‰,均分布在我国大气降水线及当地大气降水线附近,表明该地区主要是大气降水成因。通过H、O同位素计算补给区温度,地热水补给高程,以及冷泉及河流补给高程,推测出补给区可能为袍木寨背斜一带及红石走滑断裂及其断裂束附近的碳酸盐岩裸露地区。氚盈余参数d表明石阡地区大多数地热水埋深较浅,循环径流时间较短,地质环境处于开放与半开放之间,水-岩反应作用相对较弱。  相似文献   

哀牢山中段镇沅金矿晚二叠世花岗斑岩U-Pb年代学、岩石地球化学及其构造意义     

张垚垚  张达  陈宣华  莫宣学  赵泽南  霍海龙 《岩石学报》2021,37(6):1674-1690

云南镇沅地区位于哀牢山构造带中段,是古特提斯哀牢山洋关闭及碰撞造山的关键部位。本文对该地区出露的花岗斑岩进行了年代学、岩石地球化学与同位素地球化学研究。锆石U-Pb年代学给出加权平均年龄为253.3±2.0Ma,表明花岗斑岩形成于晚二叠世。3个花岗斑岩脉共5个样品分析结果表明,其SiO_2含量65.30%～70.79%,全碱含量(K_2O+Na_2O)3.53%～4.39%,Al_2O_3含量13.42%～16.40%,为高钾钙碱性亚碱性系列岩石,成分上与花岗闪长岩类似,为S型花岗岩。稀土元素含量较低,轻重稀土分异程度较高,稀土配分曲线为右倾,无明显Ce异常,具弱负Eu异常,微量元素配分曲线为右倾,大离子亲石元素相对富集,高场强元素相对亏损,与典型地壳相一致。锆石Hf同位素ε_(Hf)(t)为-1.0～4.1,显示岩浆源区为亏损地幔和古老地壳物质部分熔融。岩石大地构造环境分析表明,该花岗斑岩形成于晚二叠世同碰撞构造环境。  相似文献   

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples     

Wei‐Xin Lv  Hao‐Ming Yin  Meng‐Shu Liu  Fang Huang  Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.  相似文献   

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis     

Alicja Wudarska  Ewa S&#x;aby  Michael Wiedenbeck  Jaime D. Barnes  Magali Bonifacie  Neil C. Sturchio  Grard Bardoux  Frdric Couffignal  Johannes Glodny  Linnea Heraty  Timm John  Christof Kusebauch  Sathish Mayanna  Franziska D. H. Wilke  Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.  相似文献   

羌塘盆地热觉茶卡-藏夏河地区泉水水化学特征及其地质意义          下载免费PDF全文

曾胜强  陈文彬  冯兴雷 《沉积与特提斯地质》2021,41(4):536-543

泉水的水化学特征可以反映氧化-还原环境和水动力条件,近年来被广泛地用于石油、天然气以及天然气水合物的找矿工作中。本文对羌塘盆地热觉茶卡—藏夏河地区37处泉水和13件地表水进行了水化学特征、水溶性烃类气体特征和水中氢氧同位素特征分析,结果表明,羌塘盆地热觉茶卡—藏夏河地区的水型主要为Na₂SO₄型和MgCl₂型,其次为NaHCO₃型和CaCl₂型。矿化度普遍较高,说明该区具有较好的保存条件。铵根离子的平均含量为0.895 g/g,在藏夏河地区高达7.381 g/g,表明在藏夏河东部地区有机质相对较为丰富,这与区域上发育的富有机质页岩结果一致。氢氧同位素结果显示,该区水体的氢氧同位素落在了大气降水线附近,表明水体的来源主要受大气降水的补给。另外,采集的9个泉水样品中均检测出一定含量的水溶甲烷,在白云湖地区的甲烷含量相对较高,显示出较好的油气潜力。综合研究表明,藏夏河东和白云湖地区具有良好的油气烃源岩条件,保存条件较好,显示出良好的油气和天然气水合物资源前景。  相似文献   

扬子陆块西缘江浪穹窿超基性岩的成因:锆石U-Pb定年、岩石地球化学及Sr-Nd同位素          下载免费PDF全文

代堰锫  李同柱  张惠华 《沉积与特提斯地质》2021,41(4):573-584

江浪穹窿位于扬子陆块西缘,本文作者在穹窿南部新发现一套侵入于二叠系及志留系的超基性岩,岩石主要由蛇纹石(约60%)、橄榄石(约30%)和少量磁铁矿(约5%)、角闪石(约5%)组成。为探讨超基性岩的成因,本文进行了LA-ICP-MS锆石U-Pb定年、岩石地球化学及Sr-Nd同位素研究。定年结果表明,超基性岩中发育大量2427~430 Ma的捕获锆石,最年轻一组岩浆锆石²⁰⁶Pb/²³⁸U加权平均年龄为222.3±4.4 Ma(MSWD=1.9,n=6)。主微量元素分析显示岩石：(1)具有低的SiO₂含量(46.76%~39.07%)、高的Mg#值(82.3~74.0)与Cr、Co、Ni丰度;(2)稀土元素含量(ΣREE平均31.8 μg/g)与(La/Yb)_N值(5.26~1.38)偏低,稀土配分型式较为平坦,具有较弱的Ce负异常(Ce/Ce^*=0.80~0.67);(3)富集大离子亲石元素Rb、Ba和U,亏损高场强元素Zr和Hf;(4)(Th/Yb)_PM值(29.8~1.56)、(Th/Ta)_PM值(0.22~0.03)、(La/Nb)_PM值(1.91~0.39)及La/Sm值(5.88~1.11)较低。Sr-Nd同位素分析显示,超基性岩具有较低的(⁸⁷Sr/⁸⁶Sr)_i值(0.706872~0.702598)和高的ε_Nd(t)值(8.02~5.64),成分接近于亏损地幔和岛弧玄武岩,计算表明地壳物质的混染程度低于5%。结合前人研究成果,本文认为超基性岩结晶年龄为222.3 Ma,可能形成于古特提斯洋闭合阶段的岛弧背景;原始岩浆来自高度部分熔融的地幔源区,上升侵位过程中可能经历了铬铁矿与橄榄石的分离结晶作用。此外,捕获锆石的年龄谱反映江浪穹窿很可能存在太古宙—古元古代变质基底,并且具有Rodinia超大陆会聚—裂解以及泛非事件的地质年龄记录。  相似文献   

Composition and origin of the volatile components released from the Pesyanoe aubrite by stepwise crushing and heating     

《Chemie der Erde / Geochemistry》2021,81(1):125686

Aubrites are achondritic meteorites (enstatite pyroxenites) that were formed in highly reduced magmatic environments on a differentiated parent body sharing a common oxygen isotope reservoir with enstatite chondrites (EC), Earth and Moon, and could be considered as a geochemical model of the early proto-Earth. Some pyroxenes of the Pesyanoe aubrite have high abundance of gaseous inclusions, captured during the crystallization of the rocks. Investigation of the inclusions by IR spectroscopy reveals presence of OH⁻ groups and C–H bonds. The former are assigned to protonated point defects in enstatite lattice and the latter to compounds occupying void walls. Molecular water and CO₂ were not observed. Volatile components released from the samples of the Pesyanoe enstatite by stepwise crushing and heating are composed of CO₂, H₂O and a non-condensable phase. Hydrogen isotopic composition of volatiles extracted in form of molecular water in Px-separates varies in the range δD = −61 – −84‰ with mean value of δD = −73 ± 16‰ VSMOW and is within the ranges of ECs and Earth’s mantle. The total abundance of H₂ in the pyroxene of Pesyanoe were estimated as at least 0.047 ppm that is too low in comparison with that of enstatite chondrites (≥30 ppm H₂) and could indicate nearly complete degassing of the Pesyanoe primitive precursor material during the Pesyanoe parent body accretion or a mantle degassing in igneous differentiation process. In a last case a primitive precursor could have D/H ratio different from that of enstatite chondrites.  相似文献   

Rb–Sr dating of sulfides and S–Pb isotopic study of the Bayanbaolege Ag polymetallic deposit,Inner Mongolia,NE China     

《Chemie der Erde / Geochemistry》2021,81(1):125724

The large-scale Bayanbaolege Ag polymetallic deposit is situated in the Tuquan–Linxi Fe-Sn-Cu-Pb-Zn-Ag metallogenic sub-belt in eastern slopes of the southern Great Xing’an Range, NE China. The sulfide-quartz vein-type orebodies in the deposit are hosted primarily in the Early Cretaceous granodiorite porphyry and Late Permian strata. Three primary paragenetic stages of veining have been identified: (I) arsenopyrite- pyrite-quartz stage, (II) pyrite-sphalerite-quartz stage, and (III) galena-silver minerals (pyrargyrite, argentite, and pearceite)-calcite stage. The Rb–Sr dating of sulfides yielded an isochron age of 129.9 ± 2.9 Ma (MSWD = 2.1) for the sphalerite, which constrains the mineralization age to the Early Cretaceous. Rb and Sr concentrations in the sulfides ranged from 0.0940 to 1.0294 ppm and 0.0950–3.3818 ppm, respectively. The initial ⁸⁷Sr/⁸⁶Sr value of the sphalerite was 0.70852 ± 0.00018, indicating that the mineralized materials were derived from the mixed crust-mantle source area. S isotope analysis showed that the δ³⁴S values of the sulfide samples varied in a narrow range, from −1.5‰ to +1.3‰ (mean −0.65‰), indicating a magmatic S source. Pb isotopic ratios of the sulfides (²⁰⁶Pb/²⁰⁴Pb = 18.306–18.416, ²⁰⁷Pb/²⁰⁴Pb = 15.524–15.605, ²⁰⁸Pb/²⁰⁴Pb = 38.095–38.479) and the granodiorite porphyry (²⁰⁶Pb/²⁰⁴Pb = 18.341–18.933, ²⁰⁷Pb/²⁰⁴Pb = 15.539–15.600, ²⁰⁸Pb/²⁰⁴Pb = 38.134–38.944) reflect that the ore-forming materials originated from contemporaneous magma with Early Cretaceous granodiorite porphyry. This study of the Bayanbaolege deposit and other hydrothermal deposits in the area provides compelling evidence that the widespread Mesozoic magmatism and mineralization in the southern Great Xing’an Range occurred in an intracontinental extensional tectonic setting, which was associated with the westward subduction of the paleo-Pacific plate.  相似文献   

柴达木盆地那棱格勒河及其尾闾盐湖锂成矿物源：来自水化学和锶、硫同位素证据   总被引：2，自引：0，他引：2  

李庆宽  王建萍  吴蝉  樊启顺  秦占杰  陈亮  魏海成  都永生  袁秦  李建森  山发寿 《地质学报》2021,95(7):2169-2182

柴达木盆地那棱格勒河尾闾盐湖（一里坪干盐滩、东台吉乃尔盐湖、西台吉乃尔盐湖和察尔汗盐湖别勒滩区段）赋存了我国目前最大的卤水锂矿床。那棱格勒河及其尾闾盐湖锂的物源仍存在一定争议,主要有围岩风化、古湖残留、含盐系地层淋滤、油田水、深部水等,目前缺乏有力的地球化学证据。本文系统采集了那棱格勒河流域及其尾闾盐湖不同水体样品16件,分析了其主、微量元素含量及锶、硫同位素组成。结合前人的研究成果,对区域水体中锂的来源进行了探讨,得出结论如下：那棱格勒河水锂含量（0. 45~0. 79 mg/L）比楚拉克阿拉干河支流（0. 00~0. 05 mg/L）高出一个数量级,其高锂含量主要受洪水河支流的补给;洪水河高锂含量与其上游热泉水的补给有关,该热泉水锂、锶含量高、 87 Sr/ 86 Sr比值偏高, δ 34 S值偏低,与青藏高原典型热泉水地球化学特征（锂含量0. 4~34. 8 mg/L,锶含量0. 07~4. 24 mg/L, 87 Sr/ 86 Sr比值0. 71224~0. 71259, δ 34 S值- 10. 6‰~7. 6‰）较一致。那棱格勒河水（0. 71170）和尾闾盐湖卤水（0. 71143~0. 71156）相似的 87 Sr/ 86 Sr比值,以及研究区河、湖水硫同位素组成符合主要蒸发浓缩过程 δ 34 S值逐渐下降的变化趋势,均证明研究区尾闾盐湖卤水锂资源主要受那棱格勒河的补给;而古湖残留水、盆地西部含盐系地层淋滤水或油田水具有明显不同的水化学特征和锶、硫同位素组成,这些水体对研究区尾闾盐湖锂补给的贡献较小,可忽略不计。  相似文献